Chemistry · Factors affecting equilibrium: concentration, pressure, temperature, the effect of catalyst, Le Chatelier's principle

The degree of dissociation of

The degree of dissociation of \( \boldsymbol{P C l}_{5} \)

  • A. increases with increasing pressure
  • B. decreases with increasing pressure
  • C. no effect on change in pressure
  • D. decreases with decreasing pressure

Step-by-step solution

The dissociation of PCl5 is PCl5(g) ⇌ PCl3(g) + Cl2(g), which increases the number of moles from 1 to 2. According to Le Chatelier's principle, increasing pressure shifts the equilibrium toward the side with fewer moles (reactants), thus decreasing the degree of dissociation.
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