Chemistry · Amines: Nomenclature, classification, structure, basic character and identification of primary, secondary and tertiary amines and their basic character

How many total isomeric amines are possible having molecular formula which gives

How many total isomeric amines are possible having molecular formula \( C_{4} H_{11} N \) which gives a bad smelling compound with \( \boldsymbol{C} \boldsymbol{H} \boldsymbol{C l}_{3}+\boldsymbol{K} \boldsymbol{O H} ? \)

  • A. Five
  • B. Six
  • C. seven
  • D. Eight

Step-by-step solution

The carbylamine reaction (with CHCl3 + KOH) is specific to primary amines. The molecular formula C4H11N corresponds to primary amines: n-butylamine, sec-butylamine (chiral, two enantiomers), isobutylamine, and tert-butylamine. Including stereoisomers, there are 5 isomeric primary amines.
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