Chemistry · Phenols: Acidic nature, electrophilic substitution reactions, halogenation, nitration and sulphonation, Reimer Tiemann reaction

Which statement is INCORRECT.

Which statement is INCORRECT.

  • A. Phenol has smaller dipolemoment than methanol.
  • B. Haloarenes are insoluble in water but are soluble in benzene.
  • C. Chloroform contains chlorine but gives no reaction with \( A g N O_{3} \) solution.
  • D. Ethanol has much lower pka value than phenol.

Step-by-step solution

Phenol is more acidic than ethanol due to resonance stabilization of phenoxide ion. pKa of phenol is ~10, while ethanol is ~16, so ethanol has a higher pKa, not lower. Therefore, statement D is incorrect.
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