Chemistry · Colligative properties of dilute solutions: a relative lowering of vapour pressure, depression of freezing point, the elevation of boiling point and osmotic pressure

Assertion Micelles are formed by surfactant molecules above the critical micella

Assertion Micelles are formed by surfactant molecules above the critical micellar concentration (CMC). Reason The conductivity of solution having surfactant molecules decreases sharply at the CMC.

  • A. Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
  • B. Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
  • C. Assertion is correct but Reason is incorrect
  • D. Assertion is incorrect but Reason is correct

Step-by-step solution

The assertion is correct: micelles form above CMC. The reason is also correct: conductivity increases with surfactant concentration but at CMC, the rate of increase decreases (i.e., slope decreases sharply) due to micelle formation. The reason explains the assertion because the sharp decrease in conductivity slope is a direct consequence of micelle formation, indicating that micelles begin to form at CMC.
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