Chemistry · Isomerism: structural and stereoisomerism
In isomeric alkyl halides:
In isomeric alkyl halides:
- A. the branch chain isomer have relatively high boiling point as compared to its straight chain isomer
- B. the branch chain isomer have relatively low boiling point as compared to its straight chain isomer
- C. the branch chain isomer boiling point equal to its straight chain isomer
- D. none of these
Step-by-step solution
In isomeric alkyl halides, branching reduces the surface area, leading to weaker van der Waals forces and thus lower boiling points. Therefore, branched chain isomers have lower boiling points than their straight chain isomers.
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