Chemistry · JEE

Important Questions: Emf of a Galvanic cell and its measurement, Nernst equation and its applications, relationship between cell potential and Gibbs' energy change for JEE

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Syllabus context

Part of Redox Reactions and Electrochemistry in JEE Main Chemistry.

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Q1ChemistryUnit 7: Redox Reactions and Electrochemistry

Which of the following changes will cause the free energy of a cell reaction to decrease?

\boldsymbol{Z} \boldsymbol{n} \mid \boldsymbol{Z} \boldsymbol{n} \boldsymbol{S} \boldsymbol{O}_{4}(\boldsymbol{a} \boldsymbol{q})\left(\boldsymbol{x}_{1} \boldsymbol{M}\right) \| \boldsymbol{H} \boldsymbol{C l}(\boldsymbol{a} \boldsymbol{q})\left(\boldsymbol{x}_{2} \boldsymbol{N}\right.

This question has multiple correct options

Q2ChemistryUnit 7: Redox Reactions and Electrochemistry

Assertion In the Daniel cell, if concentration of

C u^{2+}

and

Z n^{2+}

ions are doubled, the emf of the cell will not change. Reason f the concentration of ions in contact with the metals is doubled, the electrode potential is doubled.

Q3ChemistryUnit 7: Redox Reactions and Electrochemistry

For the reaction:

\boldsymbol{F} \boldsymbol{e}^{2+}(\boldsymbol{a} \boldsymbol{q})+\boldsymbol{A} \boldsymbol{g}^{+}(\boldsymbol{a} \boldsymbol{q}) \longrightarrow \boldsymbol{A} \boldsymbol{g}(\boldsymbol{s})+

\boldsymbol{F} \boldsymbol{e}^{+\boldsymbol{3}}(\boldsymbol{a} \boldsymbol{q})

Predict which change will decrease the cell voltage?

Q4ChemistryUnit 7: Redox Reactions and Electrochemistry

Calculate

\boldsymbol{E}_{\text {cell}}

\boldsymbol{P t}(\boldsymbol{s})\left|\boldsymbol{H}_{2}(\boldsymbol{g})_{1 a t m}\right| \boldsymbol{H} \boldsymbol{A}_{\left(\boldsymbol{K}_{a}=10^{-7}\right)} \mathbf{1} \boldsymbol{M} \| \boldsymbol{H} \boldsymbol{B}_{(\boldsymbol{k}}

Q5ChemistryUnit 7: Redox Reactions and Electrochemistry

The standard cell potential for

Z n\left|Z n^{2+}\right|\left|C u^{2+}\right| C u

1.10 V .

When the cell is completely discharged,

\log \left[Z n^{2+}\right] /\left[C u^{2+}\right]

is closest to:

Q6ChemistryUnit 7: Redox Reactions and Electrochemistry

The standard oxidation potential of Zn referred to SHE is

0.76 \mathrm{V}

and that of

\mathrm{Cu}

-0.34 V

25^{\circ} \mathrm{C} .

When excess of Zn is added to

C u S O_{4}, Z n

displaces

C u^{2+}

till equilibrium is reached. What is the ratio of

Z n^{2+}

C u^{2+}

ions at equilibrium? Express the ans in the form

\left[Z n^{2+}\right] /\left[C u^{2+}\right]=k \times 10^{37},

and find

k

Q7ChemistryUnit 7: Redox Reactions and Electrochemistry

The equilibrium constant for the reaction

\boldsymbol{S} \boldsymbol{r}(\boldsymbol{s})+\boldsymbol{M} \boldsymbol{g}^{+2}(\boldsymbol{a} \boldsymbol{q}) \rightleftharpoons \boldsymbol{S} \boldsymbol{r}^{+2}(\boldsymbol{a} \boldsymbol{q})+

M g(s)

4 \times 10^{12}

25^{\circ} C

The

E^{o}

for a cell made up of the

\boldsymbol{S} \boldsymbol{r} \mid \boldsymbol{S} \boldsymbol{r}^{+2}

and

\boldsymbol{M} \boldsymbol{g}^{+2} \mid \boldsymbol{M} \boldsymbol{g}

half cells

(\log

\mathbf{2}=\mathbf{0 . 3})

Q8ChemistryUnit 7: Redox Reactions and Electrochemistry

The

E_{\text {cell}}

for a given cell is 1.2346 and

1.2340 V

300 \mathrm{K}

and

310 \mathrm{K}

respectively. Calculate the change in entropy during the cell reaction if the redox change involves three electrons.

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