Chemistry · JEE

Elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units Concepts for JEE

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Master Elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units by understanding definitions, standard results, and typical JEE question patterns — then practise with syllabus-aligned MCQs on Goodmarks.

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Concept explainer

Elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units is a core JEE Main Chemistry subtopic under Chemical Kinetics. Master the definitions, standard results, and typical MCQ patterns tested in JEE Main and Advanced.

Key points

  • Understand the definition and scope of Elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units in the JEE syllabus
  • Memorise key formulas and standard results linked to Elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units
  • Practise 20–40 syllabus-aligned MCQs with step-by-step solutions

JEE tips

  • Revise Elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units with a one-page formula sheet before attempting mixed tests
  • After each practice set, log mistakes specific to Elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units and reattempt after 48 hours

Common trap

Students often rush Elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units questions without checking units, sign conventions, or boundary conditions — always verify assumptions before calculating.

Free sample questions

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Q1ChemistryUnit 8: Chemical Kinetics
A reaction A+BCA+B \rightarrow C is second order with respect to AA and independent of BB The rate expression for the reaction is:
Q2ChemistryUnit 8: Chemical Kinetics
Statement - I : The molecularity of the reaction H2+Br22HBr\boldsymbol{H}_{2}+\boldsymbol{B} \boldsymbol{r}_{2} \rightarrow 2 \mathrm{HBr} is 2 Statement - II: The order of this reaction is 3/23 / 2
Q3ChemistryUnit 8: Chemical Kinetics
The choices below are some of the proposed steps of a reaction mechanism. Which step is least likely to be the ratedetermining step of the mechanism?
Q4ChemistryUnit 8: Chemical Kinetics
Which one of the following statements for order of reaction is not correct?
Q5ChemistryUnit 8: Chemical Kinetics
In the hydrolysis of organic chloride in the presence of a large excess of water, RCl+H2OROH+HCl\boldsymbol{R C l}+\boldsymbol{H}_{2} \boldsymbol{O} \rightarrow \boldsymbol{R O H}+\boldsymbol{H} \boldsymbol{C l}
Q6ChemistryUnit 8: Chemical Kinetics
For the reaction given below, 2O3(g)3O2(g)\mathbf{2} \mathbf{O}_{\mathbf{3}}(\mathbf{g}) \rightarrow \mathbf{3} \mathbf{O}_{\mathbf{2}}(\mathbf{g}) Step:O3(g)O2(g)+O(g)\operatorname{Step} \mid: \mathbf{O}_{3}(\mathbf{g}) \rightarrow \mathbf{O}_{2}(\mathbf{g})+\mathbf{O}(\mathbf{g}) Step 2:O3(g)+Oslow 2O2(g)2: \mathrm{O}_{3}(\mathrm{g})+\mathrm{O} \rightarrow^{\text {slow }} 2 \mathrm{O}_{2}(\mathrm{g}) Statement I: The molecularity of the first step is 1 and of the second step is 2 Statement-II: O(g)O(g) is an intermediate and rate of reaction is K[O3]2[O2]1\mathbf{K}\left[\mathbf{O}_{3}\right]^{2}\left[\mathbf{O}_{2}\right]^{-1} and order of reaction is 1
Q7ChemistryUnit 8: Chemical Kinetics
Which of the following statement is true for the reaction, H2+Br22HBr\boldsymbol{H}_{2}+\boldsymbol{B} \boldsymbol{r}_{2} \rightarrow \boldsymbol{2} \boldsymbol{H} \boldsymbol{B} \boldsymbol{r} The rate law is dxdt=k[H2][Br2]1/2\frac{\boldsymbol{d} \boldsymbol{x}}{\boldsymbol{d} \boldsymbol{t}}=\boldsymbol{k}\left[\boldsymbol{H}_{2}\right]\left[\boldsymbol{B} \boldsymbol{r}_{2}\right]^{1 / 2}

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